Organic Chemistry: With Biological Applications (2nd Edition)
John E. McMurry
Language: English
Pages: 1158
ISBN: 128584291X
Format: PDF / Kindle (mobi) / ePub
Renowned for its student-friendly writing style and fresh perspective, John McMurry's ORGANIC CHEMISTRY WITH BIOLOGICAL APPLICATIONS offers full coverage of the foundations of organic chemistry--enhanced by biological examples throughout. Based on user feedback, McMurry continues to discuss the organic chemistry of biological pathways and now adds two dozen additional organic chemistry topics, as well as new problems, new illustrations, and new essays. Media integration with Organic OWL, a customizable online learning system and assessment tool, reduces faculty workload, facilitates instruction, and helps students master concepts through tutorials, simulations, and algorithmically generated homework questions.
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Propose skeletal structures for compounds that satisfy the following molecular formulas. There is more than one possibility in each case. (a) C5H12 (b) C2H7N (c) C3H6O (d) C4H9Cl Problem 1.17 The following molecular model is a representation of para-aminobenzoic acid (PABA), the active ingredient in many sunscreens. Indicate the positions of the multiple bonds, and draw a skeletal structure (gray ϭ C, red ϭ O, blue ϭ N, ivory ϭ H). para-Aminobenzoic acid (PABA) Summary Key Words antibonding.
O C H H H C O C HO HO C C C H OH H Nicotine Problems assignable in Organic OWL. Glucose H OH H exercises 1.30 1.31 Convert the following molecular formulas into structures that are consistent with the usual bonding patterns: (a) C3H8 (c) C2H6O (2 possibilities) (b) CH5N (d) C3H7Br (2 possibilities) (e) C2H4O (3 possibilities) (f) C3H9N (4 possibilities) What kind of hybridization do you expect for each carbon atom in the following molecules? CH3 (b) 2-Methylpropene, (a).
797 Synthesis of Amino Acids 800 Peptides and Proteins 802 Amino Acid Analysis of Peptides 804 detailed contents 19.6 19.7 19.8 19.9 19.10 Peptide Sequencing: The Edman Degradation 805 Peptide Synthesis 807 Protein Structure 812 Enzymes and Coenzymes 814 How Do Enzymes Work? Citrate Synthase 818 Summary 821 Summary of Reactions 822 Lagniappe—The Protein Data Bank 823 Exercises 824 Amino Acid Metabolism 20.1 20.2 20.3 20.4 20.5 20 832 An Overview of Metabolism and Biochemical Energy 833.
Ring-flip in chair cyclohexane interconverts axial and equatorial positions. What is axial (red) in the starting structure becomes equatorial in the ring-flipped structure, and what is equatorial (blue) in the starting structure is axial after ring-flip. Ring-flip Move this carbon down Ring-flip Move this carbon up As shown in Figure 4.11, a chair cyclohexane can be ring-flipped by keeping the middle four carbon atoms in place while folding the two end carbons in opposite directions. In so.
A steroid is axial or equatorial. (A substituent that is “up” is on the top face of the molecule as drawn, and a substituent that is “down” is on the bottom face.) (a) Substituent up at C3 (b) Substituent down at C7 (c) Substituent down at C11 3 H H Problems assignable in Organic OWL. CH3 11 H CH3 7 H exercises 4.52 Amantadine is an antiviral agent that is active against influenza type A infection. Draw a three-dimensional representation of amantadine showing the chair cyclohexane.